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1 article(s) from Sauvé, Geneviève

Synthesis and characterization of fluorinated azadipyrromethene complexes as acceptors for organic photovoltaics

Forrest S. Etheridge,
Roshan J. Fernando,
Sandra Pejić,
Matthias Zeller and
Geneviève Sauvé

Beilstein J. Org. Chem. 2016, 12, 1925–1938, doi:10.3762/bjoc.12.182

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Graphical Abstract

Figure 1: a) Azadipyrromethene ligand labeling positioning; b and c) chelates; d) estimated HOMO/LUMO energy ...

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Figure 2: Chemical structures of the fluorinated ADP derivatives of WS3 explored in the study.

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Scheme 1: Generic synthetic scheme for fluorinated free ligands, where L# corresponds to the desired ligand n...

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Scheme 2: Generic chelation scheme yielding WS3-based BF₂⁺ and zinc(II) complexes.

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Figure 3: TGA spectra for the zinc(II) complexes.

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Figure 4: Molar absorptivities in chloroform solutions of a) zinc(II) chelates b) BF₂⁺ chelates.

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Figure 5: Normalized absorbance from spun-coat chloroform solution on microscope glass of a) zinc(II) chelate...

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Figure 6: Cyclic voltamograms of zinc(II) chelates in 0.1 M TBAPF₆ dichloromethane solution with Fc/Fc⁺ as an...

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Figure 7: Cyclic voltamograms of BF₂⁺ chelates in 0.1 M TBAPF₆ dichloromethane solution with Fc/Fc⁺ as an int...

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Figure 8: Estimated HOMO and LUMO energy levels obtained by cyclic voltammetry from the E_1/2 values in dichlo...

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Figure 9: ORTEP drawing of Zn(L2)₂ with ellipsoids drawn at the 50% probability level and a partial labeling ...

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Figure 10: ORTEP drawing of Zn(L2)₂ with ellipsoids drawn at the 50% probability level and a partial labeling ...

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Published 29 Aug 2016

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